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I want to find the half equations in the redox reaction between chlorine gas and water?

Cl2(g) + H2O(l) -> HOCl(aq) + HCl(aq)

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Is there any way to subscript numbers and states? – Hugh Feb 17 at 0:05
Yep, use <sup>superscript text</sup> and <sub>subscript text</sub> HTML tags :) – Collin Li Feb 17 at 7:45
Thanks Colin... – Hugh Feb 17 at 9:53

1 Answer

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Assign the oxidation states to the elements.

Elemental substances assume ox state of 0, such as Al, Cl2, etc.

Neutral compounds have overall ox state of 0, like H2O: ox(H) = +1, ox(O) = -2, have 2 Hs and 1 O so overall oxidation state is 2x(+1) + (-2) = 0.

O (oxygen) in compounds usually has ox state of -2 (with some exceptions like H2O2 but not frequently encountered).

H in compound usually is +1.

In this case:

Cl in Cl2 = 0

Cl in HOCl = +1 (because H = +1, O = -2 so Cl = +1 to make the whole HOCl have ex state of 0)

Cl in HCl = -1

Oxidation:Cl2 -> HOCl

Reduction: Cl2 -> HCl

Then balance the two half equations.

Note: The book should have a dedicated chapter for this.

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